To Perpignan which is only 16 miles away. RyanAir fly daily to Prepignan from London Stansted - often offering very cheap flights. They also fly to nearby Carcassonne as do Easy Jet.

Alternatively destinations include: Toulouse (1 hour 30 mins away), Gerona (1 hour 30 mins away) and Barcelona (2 hours away) which are destinations for OpenJet.

All these airports have car hire facilities.

Click on the link below for a Michelin map showing you the route from Perpignan Airport to Collioure

Aéroport de Perpignan-Rivesaltes 66000 Perpignan - Place Jean Jaurès 66190 Collioure

E15/E17 Reims - Dijon - Lyon - Montpelier - Perpignan. Then N114 to Collioure.
(This seems to be the quickest route).

or

E402 Rouen / Le Mans, E502 to Tours, A10/E5 to Poitier and Bordeaux, E72/A62 to Toulouse, E80/A61 to Narbonne then south on E15/A9 to Perpignan and N114 to Collioure.

or

The central route - E5/A10 south of Paris to Orléans, A71/E9/E11 to Clermont-Ferrand then across the Massif Central E11 (new toll-free road) south to Béziers, join A9/E15 to Perpignan and N114 to Collioure.

The French railway (SNCF) run trains to Collioure from Perpignan and Barcelona.